Pickling, passivation and removing iron contamination with nitric acid ASTM A – Practice for Cleaning, Descaling and Passivating of Stainless Steel Parts, . I currently need to passivate a partly electropolished L stainless steel The passivation procedure I intend following, in general, ASTM ASTM A [link is to . Delstar Metal Finishing maintains high standards in stainless steel passivation, meeting the ASTM A standards. ASTM A passivation standards include.
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This process makes the part less susceptible to rust and corrosion. Range C Time mins. This standard covers both nitric and citric acid treatments.
ASTM A380 Passivation Standard
Recommended cleaning practices shall be followed for welds and weld-joint areas, specially critical applications, installed systems and post-erections. To my knowledge it is not possible to do a combination pickling and passivation. Stainless steels cannot be passivated unless the steel surface is clean and free from contamination and scale from welding operations. I agree with Lee that what you are proposing should not be a problem with the EP’d surfaces.
While the practice provides recommendations and information concerning the use of acids and other cleaning and descaling agents, it cannot encompass detailed cleaning procedures for specific types of equipment or installations. The degree of cleanness required on a surface depends on the application.
ASTM A – Stainless Steel Passivation by Keystone Finishing
For certain exceptional applications, additional requirements which are not covered by this practice may be specified upon agreement between the supplier and the purchaser.
Tests with acceptance criteria to demonstrate that the passivation procedures have been successful are listed in 7. Degreasing and general cleaning shall be accomplished by immersion in, swabbing with, or spraying with alkaline, emulsion, chelate, acid, solvent, or detergent cleaners or a combination of these; by vapor degreasing; by ultrasonics using various cleaners; by steam, with or without a cleaner; or by high-pressure water-jetting.
There are better formulations for doing what you want, however, passivstion are available on a proprietary basis. This practice covers the standard recommendations and precautions for cleaning, descaling, and passivating of new stainless steel parts, assemblies, equipment, and installed systems. Combining values from the two systems may result in non-conformance with the standard. In addition, this standard also includes citric acid treatments. These recommendations are presented as procedures for guidance when it is recognized that for a particular service it is desired to remove surface contaminants that may impair the normal corrosion resistance, or result in the later contamination of the particular stainless steel grade, or cause product contamination.
Specific treatments are however also specified. Although they apply primarily to materials in the composition ranges of the austenitic, ferritic, martensitic, and duplex stainless steels, the practices described may also be useful for cleaning other metals if due consideration is given to corrosion and possible metallurgical effects.
Precaution shall always be practiced to minimize iron contamination, in reuse of cleaning and pickling solution, in water rinsing, in circulation of cleaning passivationn and rinse water, in protection of cleaned surfaces, for safety, and disposal of used solutions and water.
In some cases, no more than degreasing or passivafion of gross contamination is necessary. It is also quite out of date and needs to be updated. Passivation is a process that removes exogenous iron or iron compounds from the surface of the stainless steel alloy.
It was at one time considered that an oxidizing treatment was necessary to establish this passive metal oxide film, but it is now accepted that this film will form spontaneously in an oxygen-containing environment providing that the surface has been thoroughly cleaned or descaled.
Lee Kremer Stellar Solutions, Inc. This abstract is a brief summary of the referenced standard. Our facilities are capable of handling both large and small parts.
Methods are described for the detection of free iron and transparent chemical and oily deposits. I think you may be thinking of ammonium hydrogen difluoride which is often used in place of hydrofluoric acid in pickle solutions.
Citric acid is a less hazardous method and has environmental benefits in terms of ‘NOx’ fume emission and waste acid disposal. In the case of classes C3 and C4, a two step process is defined, with a clean water rinse between the two steps, shown in the table below. Process Class Stainless Steel Types C1 or C2 Austenitics, austenitic precipitation hardening and duplex C3 High chromium martensitics C4 Ferritics, martensitics and martensitic precipitation hardening.
You do not need super quality water for these processes; DI or RO water will be fine. Link to Active This link will always route to the current Active version of the standard. Give us a call or visit asmt contact page to request a quote for your project today! Pickling, passivation and removing iron contamination with nitric acid Passivation treatments are sometimes specified, but it is important to consider whether this is strictly necessary or not.
The values pasisvation in each system may not be exact equivalents; therefore, each system shall be used independently of the other. Could someone confirm or deny this effect? Keystone Corporation is an industry leader in the passivation of stainless steel.
The standard notes that the high carbon martensitic stainless steels, such as C, are not suitable for acid passivation as they can be attacked or be subject to hydrogen embrittlement. Let us know if we can help. Such chemical treatment is generally not necessary for the formation of the passive metal oxide film. Having been in the metal finishing industry for nearly a century, Keystone Corporation meets the qualified standards of ASTM A and is well qualified to handle your passivation needs.
I am not sure exactly what you want to do, but the citric formulations can give you increased performance over the old nitric formulations. In order to avoid ambiguity in the setting of requirements, it may be necessary for the purchaser to define precisely the intended meaning of passivation. Visual inspection; wipe tests; residual pattern; water-break test; free iron test such as water-wetting or drying; high-humidity test; and copper sulfate test.